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Registro completo
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Biblioteca (s) : |
INIA Las Brujas. |
Fecha : |
06/06/2019 |
Actualizado : |
06/06/2019 |
Tipo de producción científica : |
Artículos en Revistas Indexadas Internacionales |
Autor : |
BESIL, N.; CESIO, V.; LUQUE, E.; PINTOS, P.; RIVAS, F.; HEINZEN, H. |
Afiliación : |
NATALIA BESIL, Universidad de la República (UdelaR)/ Facultad de Química; VERÓNICA CESIO, Universidad de la República (UdelaR)/ Facultad de Química; MAYZA ELEANA LUQUE NUÑEZ, INIA (Instituto Nacional de Investigación Agropecuaria), Uruguay; PEDRO MAXIMILIANO PINTOS RODRIGUEZ, INIA (Instituto Nacional de Investigación Agropecuaria), Uruguay; CARLOS FERNANDO RIVAS GRELA, INIA (Instituto Nacional de Investigación Agropecuaria), Uruguay; HORACIO HEINZEN, Universidad de la República (UdelaR)/ Facultad de Química. |
Título : |
Dissipation of pre-harvest pesticides on "Clementine" mandarins after open field application, and their persistence when stored under conventional postharvest conditions. |
Fecha de publicación : |
2018 |
Fuente / Imprenta : |
Horticulturae. 2018, vol.4, Issue 4:55. |
DOI : |
10.3390/horticulturae4040055 |
Idioma : |
Inglés |
Notas : |
Article history: Received: 13 October 2018 / Revised: 11 December 2018 / Accepted: 12 December 2018 / Published: 18 December 2018.
This article belongs to the Special Issue Postharvest Disease Development: Pre and/or Postharvest Practices. |
Contenido : |
ABSTRACT.
The dissipation of field-applied difenoconazole, imidacloprid, pyraclostrobin and spinosad on Clementine mandarins (Citrus clementina Hort. ex Tan.) under controlled conditions throughout the citrus production chain was assessed. At harvest, 42 days after application, the dissipation of these pesticides were 80, 92, and 48% for difenoconazole, imidacloprid, pyraclostrobin, respectively, and spinosad was below the level of detectability. At day 28 after application, spinosad was no longer detected. The model equations that best describe the dissipation curves of these pesticides on Clementine mandarins showed different patterns. Their half-life on Clementine, calculated by the best-fitted experimental data, were 19.2 day (1st-order model) for difenoconazole, 4.1 day (Root Factor (RF) 1st-order model) for imidacloprid, 39.8 day (2nd-order model) for pyraclostrobin and 5.8 day (1st-order model) for spinosad. These results are the first record of pyraclostrobin persistence on mandarins, showing a longer half-life in this matrix than those reported for any other fruit. The treated fruit were harvested and submitted to the usual postharvest treatments: first, a hypochlorite drenching was performed; as a second step, imazalil and wax were applied, and then the mandarins were stored at 4 °C. After 32 days, cold storage caused no significant effects on the residue levels of the four pesticides compared with those determined on freshly harvested mandarins. All residues were below their Codex and European Union (EU) maximum residue limit (MRL) for mandarin since the spray application day. MenosABSTRACT.
The dissipation of field-applied difenoconazole, imidacloprid, pyraclostrobin and spinosad on Clementine mandarins (Citrus clementina Hort. ex Tan.) under controlled conditions throughout the citrus production chain was assessed. At harvest, 42 days after application, the dissipation of these pesticides were 80, 92, and 48% for difenoconazole, imidacloprid, pyraclostrobin, respectively, and spinosad was below the level of detectability. At day 28 after application, spinosad was no longer detected. The model equations that best describe the dissipation curves of these pesticides on Clementine mandarins showed different patterns. Their half-life on Clementine, calculated by the best-fitted experimental data, were 19.2 day (1st-order model) for difenoconazole, 4.1 day (Root Factor (RF) 1st-order model) for imidacloprid, 39.8 day (2nd-order model) for pyraclostrobin and 5.8 day (1st-order model) for spinosad. These results are the first record of pyraclostrobin persistence on mandarins, showing a longer half-life in this matrix than those reported for any other fruit. The treated fruit were harvested and submitted to the usual postharvest treatments: first, a hypochlorite drenching was performed; as a second step, imazalil and wax were applied, and then the mandarins were stored at 4 °C. After 32 days, cold storage caused no significant effects on the residue levels of the four pesticides compared with those determined on freshly harvested mandarins. All residues were ... Presentar Todo |
Palabras claves : |
DEGRADATION DYNAMIC; LC-MS/MS; PESTICIDE RESIDUES. |
Thesagro : |
CITRUS. |
Asunto categoría : |
F01 Cultivo |
URL : |
http://www.ainfo.inia.uy/digital/bitstream/item/12791/1/horticulturae-04-00055.pdf
https://www.mdpi.com/2311-7524/4/4/55
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Marc : |
LEADER 02625naa a2200253 a 4500 001 1059829 005 2019-06-06 008 2018 bl uuuu u00u1 u #d 024 7 $a10.3390/horticulturae4040055$2DOI 100 1 $aBESIL, N. 245 $aDissipation of pre-harvest pesticides on "Clementine" mandarins after open field application, and their persistence when stored under conventional postharvest conditions.$h[electronic resource] 260 $c2018 500 $aArticle history: Received: 13 October 2018 / Revised: 11 December 2018 / Accepted: 12 December 2018 / Published: 18 December 2018. This article belongs to the Special Issue Postharvest Disease Development: Pre and/or Postharvest Practices. 520 $aABSTRACT. The dissipation of field-applied difenoconazole, imidacloprid, pyraclostrobin and spinosad on Clementine mandarins (Citrus clementina Hort. ex Tan.) under controlled conditions throughout the citrus production chain was assessed. At harvest, 42 days after application, the dissipation of these pesticides were 80, 92, and 48% for difenoconazole, imidacloprid, pyraclostrobin, respectively, and spinosad was below the level of detectability. At day 28 after application, spinosad was no longer detected. The model equations that best describe the dissipation curves of these pesticides on Clementine mandarins showed different patterns. Their half-life on Clementine, calculated by the best-fitted experimental data, were 19.2 day (1st-order model) for difenoconazole, 4.1 day (Root Factor (RF) 1st-order model) for imidacloprid, 39.8 day (2nd-order model) for pyraclostrobin and 5.8 day (1st-order model) for spinosad. These results are the first record of pyraclostrobin persistence on mandarins, showing a longer half-life in this matrix than those reported for any other fruit. The treated fruit were harvested and submitted to the usual postharvest treatments: first, a hypochlorite drenching was performed; as a second step, imazalil and wax were applied, and then the mandarins were stored at 4 °C. After 32 days, cold storage caused no significant effects on the residue levels of the four pesticides compared with those determined on freshly harvested mandarins. All residues were below their Codex and European Union (EU) maximum residue limit (MRL) for mandarin since the spray application day. 650 $aCITRUS 653 $aDEGRADATION DYNAMIC 653 $aLC-MS/MS 653 $aPESTICIDE RESIDUES 700 1 $aCESIO, V. 700 1 $aLUQUE, E. 700 1 $aPINTOS, P. 700 1 $aRIVAS, F. 700 1 $aHEINZEN, H. 773 $tHorticulturae. 2018, vol.4, Issue 4:55.
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INIA Las Brujas (LB) |
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4. | | FERRARI, V.; GIL, G.; HEINZEN, H.; ZOPPOLO, R.; IBÁÑEZ, F. Influence of Cultivar on Nutritional Composition and Nutraceutical Potential of Pecan Growing in Uruguay. Frontiers in Nutrition, 2022, volume 9, e868054. OPEN ACESS. doi: https://doi.org/10.3389/fnut.2022.868054 Article history: Received 02 February 2022; Accepted 30 May 2022; Published: 22 June 2022. -- Correspondence: Facundo Ibáñez, fibanez@inia.org.uy -- Edited by: Elena Ibañez, Institute of Food Science Research (CSIC), Spain. Reviewed by:...Tipo: Artículos en Revistas Indexadas Internacionales | Circulación / Nivel : Internacional - -- |
Biblioteca(s): INIA Las Brujas. |
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7. | | BESIL, N.; CESIO, V.; BOLOGNA, F.; LUQUE, E.; PINTOS, P.; RIVAS, C.; HEINZEN, H. Disipación de fungicidas e insecticidas utilizados en campo en el cultivo de mandarinas, naranjas y limones. In: INIA (Instituto Nacional de Investigación Agropecuaria); Programa Nacional Producción Citrícola. Resultados de investigación en Citricultura: Genética, Sanidad, Productividad. Salto (Uruguay): INIA, 2015. p. 45-49 (Serie Actividades de Difusión; 752).Biblioteca(s): INIA Las Brujas. |
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9. | | BESIL, N.; PÉREZ-PARADA, A.; BOLOGNA, F.; CESIO, M.V.; RIVAS, F.; HEINZEN, H. Dissipation of selected insecticides and fungicides applied during pre-harvest on mandarin and orange trees in Uruguay. Scientia Horticulturae, 5 April 2019, Volume 248, Pages 34-40. Article history: Received 4 October 2018 / Revised 28 December 2018 / Accepted 29 December 2018 / Available online 9 January 2019.
Funding sources: Financial support from Instituto Nacional de Investigación Agropecuaria Uruguay,...Tipo: Artículos en Revistas Indexadas Internacionales | Circulación / Nivel : Internacional - -- |
Biblioteca(s): INIA Las Brujas. |
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10. | | BESIL, N.; PÉREZ-PARADA, A.; CESIO, V.; VARELA, P.; RIVAS, F.; HEINZEN, H. Degradation of imazalil, orthophenylphenol and pyrimethanil in Clementine mandarins under conventional postharvest industrial conditions at 4 °C. Food Chemistry, 2016, v.194, p. 1132-1137. Article history: Received 16 April 2015 / Received in revised form 25 August 2015 / Accepted 25 August 2015 / Available online 29 August 2015.
Chemical compounds studied in this article: Imazalil (PubChem CID: 37175) / Orthophenylphenol...Tipo: Artículos en Revistas Indexadas Internacionales | Circulación / Nivel : Internacional - -- |
Biblioteca(s): INIA Las Brujas. |
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12. | | PREVE, F.; ABELLA, I.; PEREIRA, D.; HEINZEN, H.; GONZÁLEZ, G.; PÉREZ, A. Lanas naturales y con bajo contenido de pesticidas. Agrociencia, 2009, v. 13, no. 3, p. 86Biblioteca(s): INIA Tacuarembó. |
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13. | | GÁMBARO, A.; ROASCIO, A.; HODOS, N.; MIGUES, I.; LADO, J.; HEINZEN, H.; RIVAS, F. The impact of sensory attributes of mandarins on consumer perception and preferences. Journal of Agriculture and Food Research, December 2021, volume 6, article 100196. OPEN ACCESS. doi: https://doi.org/10.1016/j.jafr.2021.100196 Article history: Received 20 November 2020, Revised 28 June 2021, Accepted 14 August 2021, Available online 19 August 2021, Version of Record 2 September 2021.
Corresponding author: Gámbaro, A.; General Flores, Uruguay;...Tipo: Artículos en Revistas Indexadas Internacionales | Circulación / Nivel : Internacional - -- |
Biblioteca(s): INIA Las Brujas. |
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14. | | MIGUES, I.; CESIO, V.; GÁMBARO, A.; MOYNA, G.; RODRÍGUEZ, C.; LADO, J.; RIVAS, F.; HEINZEN, H. NMR metabolomics as a prediction tool for consumers acceptance of mandarins. (SI-O-7) [oral presentation]. Session I: Breeding, Genomics and Genetics. In: RIivas, F. (Ed.). IV International Symposium on Citrus Biotechnology. Book of Abstracts. Montevideo (UY): INIA. p. 17. (INIA Serie Técnica; 244).Tipo: Presentaciones Orales |
Biblioteca(s): INIA Las Brujas. |
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15. | | NIELL, S.; JESÚS, F.; PÉREZ, C.; MENDOZA, Y.; DIAZ, R.; FRANCO, J.; CESIO, V.; HEINZEN, H. QuEChERS adaptability for the analysis of pesticide residues in beehive products seeking the development of an agroecosystem sustainability monitor. Journal of Agricultural and Food Chemistry, 13 May 2015, Volume 63, Issue 18, Pages 4484-4492. Article history: Publication Date (Web): 16 Apr 2015Tipo: Artículos en Revistas Indexadas Internacionales | Circulación / Nivel : A - 1 |
Biblioteca(s): INIA La Estanzuela. |
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17. | | MIGUES, I.; RIVAS, F.; MOYNA, G.; KELLY, S. D.; HEINZEN, H. Predicting mandarin fruit acceptability: from high-field to benchtop NMR spectroscopy. Foods, 2022, volume 11, issue 16, article 2384. OPEN ACCESS. doi: https://doi.org/10.3390/foods11162384 Article history: Received 24 June 2022; Revised 29 July 2022; Accepted 1 August 2022; Published 9 August 2022.
Corresponding author: Heinzen, H.; Laboratorio de Farmacognosia y Productos Naturales, Departamento de Química Orgánica,...Tipo: Artículos en Revistas Indexadas Internacionales | Circulación / Nivel : Internacional - -- |
Biblioteca(s): INIA Las Brujas. |
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18. | | REZENDE, S.; BANCHERO, S.; MIGUES, I.; CESIO, M.V.; RIVAS, F.; HEINZEN, H.; BESIL, M.N. Variability levels of selected amino acids among mandarins produced in Uruguay. Ecletica Quimica, 2021, Volume 46, Issue 4, Pages 47-59. Gold Open Access. doi: https://doi.org/10.26850/1678-4618eqj.v46.4.2021.p47-59 Article history: Received: July 27, 2020; Accepted: July 16, 2021; Published: October 01, 2021.
Section Editor: Assis Vicente Benedetti.
Corresponding author: María Natalia Besil. Email address: nbesil@fq.edu.uyTipo: Artículos en Revistas Indexadas Internacionales | Circulación / Nivel : Internacional - -- |
Biblioteca(s): INIA Las Brujas. |
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20. | | NIELL, S.; PAREJA, L.; ASTEGGIANTE, L.G.; ROEHRS, R.; PIZZUTTI, I.R.; GARCIA, C.; HEINZEN, H.; CESIO, M.V. Development of methods for multiresidue analysis of rice post-emergence herbicides in loam soil and their possible applications to soils of different composition. Journal of AOAC International, 2010, v. 93 no.2, p. 425-431. 2-s2.0-77952781014Tipo: Artículos en Revistas Indexadas Internacionales | Circulación / Nivel : B - 1 |
Biblioteca(s): INIA Las Brujas. |
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